Evidence for Direct Transmetalation of AuIII–F with Boronic Acids,Journal of the American Chemical Society

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Evidence for Direct Transmetalation of AuIII–F with Boronic Acids
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2016-10-14 , DOI: 10.1021/jacs.6b07763
Roopender Kumar ₁ , Anthony Linden ₁ , Cristina Nevado ₁

Affiliation

The underlying reactivity of AuIII-F species with aryl boronic acids has been studied in detail taking advantage of four novel, stable difluoro-[(C^N)AuF2], arylmonofluoro-[(C^N)AuArF], and alkylmonofluoro-[(C^N)AuAlkF] gold(III) complexes, prepared and isolated in monomeric form. We provide the first experimental evidence for a direct AuIII-F/B transmetalation preceding the Csp2-Csp2 or Csp3-Csp2 bond formation.

中文翻译：

AuIII-F 与硼酸直接转移的证据

已经利用四种新型稳定的二氟-[(C^N)AuF2]、芳基单氟-[(C^N)AuArF] 和烷基单氟-[ (C^N)AuAlkF] 金 (III) 配合物，以单体形式制备和分离。我们为 Csp2-Csp2 或 Csp3-Csp2 键形成之前的直接 AuIII-F/B 金属转移提供了第一个实验证据。

更新日期：2016-10-14

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