Electrocatalytic Difunctionalization of Olefins as a General Approach to the Synthesis of Vicinal Diamines,Synlett

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Electrocatalytic Difunctionalization of Olefins as a General Approach to the Synthesis of Vicinal Diamines
Synlett ( IF 1.7 ) Pub Date : 2018-01-15 , DOI: 10.1055/s-0036-1591749
Song Lin _{1,

2} , Joseph Parry ₁ , Niankai Fu ₁

Affiliation

Vicinal diamines are highly prevalent structural motifs in therapeutic agents, bioactive natural products, and molecular catalysts. However, there are currently few unified methodological approaches for making these pertinent synthetic building blocks. This Synpacts article provides an overview of selected landmark developments in the area of olefin diamination. In particular, we highlight our recent contribution on the electrocatalytic diazidation of olefins as a general, selective, and sustainable method for the synthesis of vicinal diamines. 1 Introduction 2 Background: Intermolecular Diamination of Olefins 3 Background: Intermolecular Diazidation of Olefins 4 Electrocatalytic Diazidation of Olefins

中文翻译：

烯烃的电催化双官能化作为合成邻二胺的一般方法

连二胺是治疗剂、生物活性天然产物和分子催化剂中非常普遍的结构基序。然而，目前很少有统一的方法来制作这些相关的合成构建块。Synpacts 的这篇文章概述了烯烃二化领域选定的里程碑式发展。特别是，我们强调了我们最近对烯烃电催化重氮化的贡献，作为合成连二胺的通用、选择性和可持续的方法。1 引言 2 背景：烯烃的分子间重氮化 3 背景：烯烃的分子间重氮化 4 烯烃的电催化重氮化

更新日期：2018-01-15

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