An air-stable mononuclear complex of bis(pentamethylcyclopentadienyl) zirconium pentafluorbezenesulfonate was successfully synthesized by treating C₆F₅SO₃Ag with [(CH₃)₅Cp]₂ZrCl₂, which showed the cationic uninuclear structure of [{(CH₃)₅Cp}₂Zr(CH₃CN)₂(H₂O)][OSO₂C₆F₅]₂·CH₃CN (1) confirmed by the X-ray analysis. Complex 1 was also characterized by other techniques and found to have the good nature of air-stability, water tolerance, thermally-stability and strong Lewis-acidity. Moreover, the complex showed high catalytic activity and recyclability in catalytic epoxide ring-opening reactions by amines or alcohols. This catalytic system affords a simple and efficient approach for synthesis of β-amino alcohols or β-alkoxy alcohols.

用[（CH ₃）₅ Cp] ₂ ZrCl ₂处理C ₆ F ₅ SO ₃ Ag，成功合成了双（五甲基环戊二烯基）五氟苯磺酸锌锆的空气稳定的单核配合物，显示[[（（CH ₃）通过X射线分析证实了₅ Cp} ₂ Zr（CH ₃ CN）₂（H ₂ O）] [OSO ₂ C ₆ F ₅ ] ₂ · CH ₃ CN（1）。综合大楼1还通过其他技术对其进行了表征，发现具有良好的空气稳定性，耐水性，热稳定性和强路易斯酸度。此外，该络合物在胺或醇的催化环氧化物开环反应中显示出高催化活性和可回收性。该催化体系为合成β-氨基醇或β-烷氧基醇提供了一种简单而有效的方法。