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The chemistry of tetrafluoroallene: nucleophilic addition reactions with phenols and amines
Journal of Fluorine Chemistry ( IF 1.7 ) Pub Date : 1 October 2003 , DOI: 10.1016/s0022-1139(03)00133-7
Ji-Chang Xiao , Qing-Yun Chen

Treatment of tetrafluoroallene or its precursor, ICF2CH2CF2I, with phenols in the presence of K2CO3 gave the corresponding unsaturated ethers. Tetrafluoroallene also reacted readily with amines in THF at room temperature to afford 3,3,3-trifluoropropionamides.

中文翻译:

四氟丙二烯的化学:与酚和胺的亲核加成反应

在K 2 CO 3存在下用苯酚处理四氟丙二烯或其前体ICF 2 CH 2 CF 2 I,得到相应的不饱和醚。在室温下,四氟丙烯也容易与胺在THF中反应,得到3,3,3-三氟丙酰胺。
更新日期:2017-01-31
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