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Kinetics of Alkylation of p-Cresol with Isobutylene Catalyzed by Sulfated Zirconia
Industrial & Engineering Chemistry Research ( IF 3.8 ) Pub Date : March 7, 1996 , DOI: 10.1021/ie940340r
Ganapati D. Yadav 1 , Tushar S. Thorat 1
Affiliation  

Absorption of isobutylene in p-cresol to prepare butylated hydroxytoluene (BHT), an important antioxidant, has been studied by using solid sulfated zirconia. Absorption is accompanied by complex chemical reactions. Detailed theoretical and experimental analysis of this system is reported here, and kinetic parameters have been established. Effects of various parameters such as partial pressure of isobutylene, catalyst loading, particle size, and temperature on the rates of reaction have been analyzed.

中文翻译:

硫酸锆催化异丁烯甲酚的烷基化反应动力学

已经通过使用固体硫酸化氧化锆研究了异丁烯在甲酚中的吸收以制备重要的抗氧化剂丁基化羟基甲苯(BHT)。吸收伴随着复杂的化学反应。本文报道了该系统的详细理论和实验分析,并建立了动力学参数。分析了各种参数,例如异丁烯的分压,催化剂的负载量,粒径和温度对反应速率的影响。
更新日期:2017-01-31
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