当前位置:
X-MOL 学术
›
Tetrahedron
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
A novel tert-butoxycarbonylation reagent: 1-tert-butoxy-2-tert-butoxycarbonyl-1,2-dihydroisoquinoline (BBDI)
Tetrahedron ( IF 2.1 ) Pub Date : 11 December 2006 , DOI: 10.1016/j.tet.2006.09.063 Yukako Saito , Hidekazu Ouchi , Hiroki Takahata
Tetrahedron ( IF 2.1 ) Pub Date : 11 December 2006 , DOI: 10.1016/j.tet.2006.09.063 Yukako Saito , Hidekazu Ouchi , Hiroki Takahata
The use of 1-tert-butoxy-2-tert-butoxycarbonyl-1,2-dihydroisoquinoline (BBDI) as a tert-butoxycarbonylation reagent for acidic proton-containing substrates such as phenols, aromatic and aliphatic amines hydrochlorides, and aromatic carboxylic acids in the absence of a base is described. The reactions proceed chemoselectively in high yield under mild conditions.
中文翻译:
一种新型的叔丁氧基羰基化试剂:1-叔丁氧基-2-叔丁氧基羰基1,2-二氢异喹啉(BBDI)
1-叔丁氧基-2-叔丁氧基羰基-1,2-二氢异喹啉(BBDI)作为叔丁氧基羰基化试剂用于酸性质子质底物(例如苯酚,芳族和脂肪族胺盐酸盐以及芳香族羧酸)的用途描述了不存在碱的情况。在温和条件下,该反应以高产率进行化学选择。
更新日期:2017-01-31
中文翻译:
一种新型的叔丁氧基羰基化试剂:1-叔丁氧基-2-叔丁氧基羰基1,2-二氢异喹啉(BBDI)
1-叔丁氧基-2-叔丁氧基羰基-1,2-二氢异喹啉(BBDI)作为叔丁氧基羰基化试剂用于酸性质子质底物(例如苯酚,芳族和脂肪族胺盐酸盐以及芳香族羧酸)的用途描述了不存在碱的情况。在温和条件下,该反应以高产率进行化学选择。