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A novel tert-butoxycarbonylation reagent: 1-tert-butoxy-2-tert-butoxycarbonyl-1,2-dihydroisoquinoline (BBDI)
Tetrahedron ( IF 2.1 ) Pub Date : 11 December 2006 , DOI: 10.1016/j.tet.2006.09.063
Yukako Saito , Hidekazu Ouchi , Hiroki Takahata

The use of 1-tert-butoxy-2-tert-butoxycarbonyl-1,2-dihydroisoquinoline (BBDI) as a tert-butoxycarbonylation reagent for acidic proton-containing substrates such as phenols, aromatic and aliphatic amines hydrochlorides, and aromatic carboxylic acids in the absence of a base is described. The reactions proceed chemoselectively in high yield under mild conditions.

中文翻译:

一种新型的氧基羰基化试剂:1-丁氧基-2-丁氧基羰基1,2-二氢异喹啉(BBDI)

1-丁氧基-2-丁氧基羰基-1,2-二氢异喹啉(BBDI)作为氧基羰基化试剂用于酸性质子质底物(例如苯酚,芳族和脂肪族胺盐酸盐以及芳香族羧酸)的用途描述了不存在碱的情况。在温和条件下,该反应以高产率进行化学选择。
更新日期:2017-01-31
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