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An efficient preparation of N-per- (or poly)fluorophenyl pyrroles and N-fluoroalkanesulfonyl pyrroles
Tetrahedron ( IF 2.1 ) Pub Date : 24 November 2003 , DOI: 10.1016/j.tet.2003.09.078
Shizheng Zhu , Xinyuan Liu , Shaowu Wang

Hetero-Diels–Alder reaction of N-sulfinyl per- (or poly)fluoroaniline and N-sulfinylfluoroalkanesulfonyl amine with 1,3-dienes affords the corresponding cycloadduct 3,6-dihydro-1,2-thiazine-1-oxide which is readily converted to N-per- (or poly)fluorophenyl pyrrole and N-fluoroalkanesulfonyl pyrrole under mild reaction conditions in good yields.

中文翻译:

N-全(或多)氟苯基吡咯和N-氟烷磺酰基吡咯的有效制备

N-亚磺酰全(或聚)氟苯胺和N-亚磺酰基氟烷烃磺酰基胺与1,3-二烯的杂Diels-Alder反应可得到相应的环加合物3,6-二氢-1,2-噻嗪-1-氧化物在温和的反应条件下,以良好的收率将其转化为N-全(或多)氟苯基吡咯和N-氟代烷磺酰基吡咯。
更新日期:2017-01-31
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