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Binuclear molybdenum alkoxide as the versatile catalyst for the conversion of carbon dioxide
Green Chemistry ( IF 9.3 ) Pub Date : 2017-12-29 00:00:00 , DOI: 10.1039/c7gc03372a
Jing-Huo Chen 1, 2, 3, 4, 5 , Cheng-Hua Deng 1, 2, 3, 4, 5 , Sheng Fang 1, 2, 3, 4, 5 , Jian-Gong Ma 1, 2, 3, 4, 5 , Peng Cheng 1, 2, 3, 4, 5
Affiliation  

The triply bonded dimolybdenum compound, Mo2(OtBu)6 (1), was investigated as a homogeneous catalyst for the conversion of CO2. The compound 1 acted as a rare example of a versatile catalyst with an impressive ability to transform CO2 into various valuable products, including propiolic acids, cyclic carbonates, and benzo[d]thiazole- and benzo[d]oxazolecarboxylic acids, in high yields with short reaction times and excellent selectivity at ambient pressure and low temperatures (25–75 °C). This is the first report of the application of a metal–metal bond-containing species in the catalytic conversion of CO2.

中文翻译:

双核烷醇钼用作二氧化碳转化的通用催化剂

研究了三键结合的二钼化合物Mo 2(O t Bu)61)作为转化CO 2的均相催化剂。化合物1是多功能催化剂的稀有实例,具有令人印象深刻的能力,能够以高收率将CO 2转化为各种有价值的产物,包括丙酸,环状碳酸酯以及苯并[ d ]噻唑和苯并[ d ]恶唑羧酸。在环境压力和低温(25–75°C)下具有短的反应时间和出色的选择性。这是关于含金属-金属键的物质在CO催化转化中的首次报道。2
更新日期:2018-03-06
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