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Syntheses of the opioid substructures 1,2,3,4,5,6-hexahydro-2,6-methano-3-benzazocine and 2,3,4,5-tetrahydro-1,5-methano-1H-2-benzazepine
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2 March 2011 , DOI: 10.1016/j.tetlet.2010.12.072 Jotham W. Coe , Paige R. Brooks , Michael G. Vetelino , Crystal G. Bashore , Krista Bianco , Andrew C. Flick
Tetrahedron Letters ( IF 1.5 ) Pub Date : 2 March 2011 , DOI: 10.1016/j.tetlet.2010.12.072 Jotham W. Coe , Paige R. Brooks , Michael G. Vetelino , Crystal G. Bashore , Krista Bianco , Andrew C. Flick
Concise syntheses of 1,2,3,4,5,6-hexahydro-2,6-methano-3-benzazocine (12) and 2,3,4,5-tetrahydro-1,5-methano-1H-2-benzazepine (18) are described and involve an intramolecular Friedel–Crafts alkylation and an intramolecular Heck cyclization as their respective key ring-forming steps.
中文翻译：
阿片样物质亚基1,2,3,4,5,6-hexahydro-2,6-methano-3-benzazocine和2,3,4,5-tetrahydro-1,5-methano-1 H -2-的合成苯并ze庚因
1,2,3,4,5,6-hexahydro-2,6-methano-3-benzazocine（12）和2,3,4,5-tetrahydro-1,5-methano-1 H -2的简明合成描述了苯并ze庚因（18），涉及分子内弗瑞德-克来福特烷基化和分子内Heck环化为它们各自的关键成环步骤。
更新日期：2017-01-31
中文翻译：
阿片样物质亚基1,2,3,4,5,6-hexahydro-2,6-methano-3-benzazocine和2,3,4,5-tetrahydro-1,5-methano-1 H -2-的合成苯并ze庚因
1,2,3,4,5,6-hexahydro-2,6-methano-3-benzazocine（12）和2,3,4,5-tetrahydro-1,5-methano-1 H -2的简明合成描述了苯并ze庚因（18），涉及分子内弗瑞德-克来福特烷基化和分子内Heck环化为它们各自的关键成环步骤。
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