The ability of easily accessible N-amino-endo-bicyclo[2.2.1]hept-5-ene-2,3-dicarboximide to undergo oxidative addition to double bonds of alkenes has been explored. The compound is active toward alkenes with electron-withdrawing groups, aryl- and alkyl-substituted alkenes, providing access to stable derivatives of N-aminoaziridine. Yields varied from 20% to 70%. No products of self-aminoaziridination were isolated.

中文翻译：

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N-氨基-内-双环[2.2.1]庚-5-烯-2,3-二甲酰亚胺在氧化氨基叠氮化反应中的作用

研究了易于获得的N-氨基-内-双环[2.2.1]庚-5-烯-2,3-二羧酸二酰亚胺经受氧化加成至烯烃双键的能力。该化合物对具有吸电子基团的烯烃，芳基和烷基取代的烯烃具有活性，从而可提供稳定的N-氨基氮丙啶衍生物。产率从20％到70％不等。没有分离出自身氨基叠氮化的产物。