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Interfacial Synthesis of Conjugated Two-Dimensional N-Graphdiyne
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2017-12-22 00:00:00 , DOI: 10.1021/acsami.7b17326 Xiaonan Kan 1 , Yanqi Ban 1 , Chenyu Wu 2 , Qingyan Pan 1 , Hui Liu 1 , Jianhui Song 1 , Zicheng Zuo 3 , Zhibo Li 1 , Yingjie Zhao 1
ACS Applied Materials & Interfaces ( IF 8.3 ) Pub Date : 2017-12-22 00:00:00 , DOI: 10.1021/acsami.7b17326 Xiaonan Kan 1 , Yanqi Ban 1 , Chenyu Wu 2 , Qingyan Pan 1 , Hui Liu 1 , Jianhui Song 1 , Zicheng Zuo 3 , Zhibo Li 1 , Yingjie Zhao 1
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We explored the interfacial synthesis of 2D N-graphdiyne films at the gas/liquid and liquid/liquid interfaces. Triazine- or pyrazine-based monomers containing ethynyl group were polymerized through the Glaser coupling reactions at interfaces. Several layered, highly ordered and conjugated 2D N-graphdiyne were obtained. Their structures were characterized by TEM, SEM, AFM, XPS, and Raman spectra. Thin films with minimum thickness of 4 nm could be prepared.
中文翻译：
共轭二维N-Graphdiyne的界面合成
我们探索了在气/液和液/液界面的二维N-graphdiyne膜的界面合成。含乙炔基的基于三嗪或吡嗪的单体通过界面处的Glaser偶联反应聚合。获得了几个分层的，高度有序的和共轭的2D N-graphdiyne。通过TEM，SEM，AFM，XPS和拉曼光谱对它们的结构进行了表征。可以制备最小厚度为4 nm的薄膜。
更新日期：2017-12-22
中文翻译：
共轭二维N-Graphdiyne的界面合成
我们探索了在气/液和液/液界面的二维N-graphdiyne膜的界面合成。含乙炔基的基于三嗪或吡嗪的单体通过界面处的Glaser偶联反应聚合。获得了几个分层的，高度有序的和共轭的2D N-graphdiyne。通过TEM，SEM，AFM，XPS和拉曼光谱对它们的结构进行了表征。可以制备最小厚度为4 nm的薄膜。
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