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A facile synthesis and novel reactions of 1, 2, 3, 4 - pentatetraene episulfides
Tetrahedron Letters ( IF 1.5 ) Pub Date : 1989 , DOI: 10.1016/s0040-4039(01)80708-5 Norihiro Tokitoh , Tomoko Suzuki , Wataru Ando
Tetrahedron Letters ( IF 1.5 ) Pub Date : 1989 , DOI: 10.1016/s0040-4039(01)80708-5 Norihiro Tokitoh , Tomoko Suzuki , Wataru Ando
Various types of 1,2,3,4-pentatetraenes 4 and 1,2,3,4-pentatetraene episulfides (1 and 2) were synthesized readily and selectively by the alkenylidene carbene addition to thioketene. Thermal, photochemical, and acid-promoted reactions of 1 and 2 resulted in a formation of novel conjugated thiones 5 and 6.
中文翻译:
1,2,3,4-戊四烯环硫化物的简便合成和新反应
通过将烯基亚基卡宾添加到硫代乙烯酮中,可以轻松,选择性地合成各种类型的1,2,3,4-戊四烯4和1,2,3,4-戊四烯环硫化物(1和2)。1和2的热,光化学和酸促进的反应导致形成新型共轭硫酮5和6。
更新日期:2017-01-31
中文翻译:
1,2,3,4-戊四烯环硫化物的简便合成和新反应
通过将烯基亚基卡宾添加到硫代乙烯酮中,可以轻松,选择性地合成各种类型的1,2,3,4-戊四烯4和1,2,3,4-戊四烯环硫化物(1和2)。1和2的热,光化学和酸促进的反应导致形成新型共轭硫酮5和6。