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Synthesis and properties of 1,6-diazaphenalenes and their charge-transfer complexes with tetracyanoquinodimethane
Tetrahedron Letters ( IF 1.5 ) Pub Date : 30 June 1997 , DOI: 10.1016/s0040-4039(97)00980-5
Koichi Tamaki , Yasushi Morita , Jiro Toyoda , Hideki Yamochi , Gunzi Saito , Kazuhiro Nakasuji

1,6-Diazaphenalene and its derivatives containing methyl, bromo, chloro, phenyl, and 2-pyridyl substituents form charge-transfer complexes with TCNQ. Relatively highly electrical conductive complexes (0.1 Scm−1) with small activation energy around 0.05 eV was obtained.

中文翻译:

1,6-二氮杂菲及其与四氰基喹二甲烷的电荷转移配合物的合成与性能

1,6-二氮杂萘及其包含甲基,溴,氯,苯基和2-吡啶基取代基的衍生物与TCNQ形成电荷转移络合物。获得了相对高电导率的复合物(0.1 Scm -1),具有约0.05 eV的小活化能。
更新日期:2017-01-31
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