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The first total synthesis and structural determination of actinopyrone A
Tetrahedron Letters ( IF 1.5 ) Pub Date : 24 July 2006 , DOI: 10.1016/j.tetlet.2006.05.028
Seijiro Hosokawa , Kazuya Yokota , Keisuke Imamura , Yasuaki Suzuki , Masataka Kawarasaki , Kuniaki Tatsuta

Actinopyrone A (1) has been synthesized by using our developed remote stereoinduction, Kocienski olefination, Horner–Wadsworth–Emmons olefination, and reductive de-conjugation of the vinylpyrone. A concise method of O-methylation to obtain the γ-pyrone has also been established.

中文翻译:

放线菌酮A的首次全合成和结构测定

通过使用我们开发的远程立体感应,Kocienski烯烃化,Horner-Wadsworth-Emmons烯烃化和乙烯基吡喃酮的还原去共轭合成了放线菌酮A(1)。还建立了一种简单的O-甲基化方法来获得γ-吡喃酮。
更新日期:2017-01-31
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