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Improved synthesis of 4,4′-diamino-2,2′-bipyridine from 4,4′-dinitro-2,2′-bipyridine-N,N′-dioxide
Tetrahedron Letters ( IF 1.5 ) Pub Date : 1 January 2004 , DOI: 10.1016/j.tetlet.2003.10.096
Paul Kavanagh , Dónal Leech

A superior synthetic route to 4,4′-diamino-2,2′-bipyridine has been developed. This procedure compares favorably with existing methods, producing 4 times the yield previously reported. In addition, mild reaction conditions are utilized, allowing a considerably more efficient production, and subsequent purification, of the diamino complex.

中文翻译:

由4,4'-二硝基-2,2'-联吡啶-NN'-二氧化物改进的4,4'-二氨基-2,2'-联吡啶的合成

已经开发出一种高级的合成4,4'-二氨基-2,2'-联吡啶的途径。该方法与现有方法相比具有优势,其产量是先前报道的4倍。另外,利用了温和的反应条件,使二氨基配合物的生产和随后的纯化大大提高了效率。
更新日期:2017-01-31
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