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Vapor Phase PvTx Measurements of Binary Blends of trans-1-Chloro-3,3,3-trifluoroprop-1-ene + Isobutane and cis-1,3,3,3-Tetrafluoroprop-1-ene + Isobutane
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : 2017-12-08 00:00:00 , DOI: 10.1021/acs.jced.7b00769
J. Steven Brown 1 , Gianluca Coccia 2 , Sebastiano Tomassetti 2 , Mariano Pierantozzi 3 , Giovanni Di Nicola 2
Affiliation  

This paper provides eighty-four PvTx data points for binary blends of trans-1-chloro-3,3,3-trifluoroprop-1-ene (R1233zd(E)) and isobutane (R600a) in the vapor phase and ninety-seven PvTx data points for binary blends of cis-1,3,3,3-tetrafluoroprop-1-ene (R1234ze(Z)) and R600a in the vapor phase. The R1233zd(E)/R600a data were recorded along six isochores (0.0499, 0.0536, 0.0927, 0.1263, 0.1431, 0.1744) m3·kg–1 for temperatures (303 < T < 383) K for six R600a mole fractions (0.125, 0.453, 0.564, 0.644, 0.746, 0.865). The R1234ze(Z)/R600a blends were recorded along five isochores (0.0759, 0.0907, 0.1272, 0.1288, 0.1520) m3·kg–1 for temperatures (303 < T < 383) K for six R600a mole fractions (0.118, 0.222, 0.427, 0.510, 0.658, 0.725). The data were regressed using several equations of state.

中文翻译:

反式-1-氯-3-3,3,3-三氟丙-1-烯+异丁烷和顺式-1,3,3,3-四氟丙-1-烯+异丁烷的二元共混物的汽相PvTx测量

本文提供了84个PvTx数据点,用于气相反式-1-氯3,3,3-三氟丙-1-烯(R1233zd(E))和异丁烷(R600a)的二元共混物和97个PvTx气相中的顺式-1,3,3,3-四氟丙-1-烯(R1234ze(Z))和R600a的二元共混物的数据点。R1233zd(E)/ R600a数据沿六个等时线(0.0499、0.0536、0.0927、0.1263、0.1431、0.1744)m 3 ·kg –1记录,温度为(303 < T <383)K,六个R600a摩尔分数(0.125, 0.453、0.564、0.644、0.746、0.865)。沿五个等时线(0.0759,0.0907,0.1272,0.1288,0.1520)m 3 ·kg记录了R1234ze(Z)/ R600a共混物对于六个R600a摩尔分数(0.118、0.222、0.427、0.510、0.658、0.725),温度(303 < T <383)K为–1。使用几个状态方程对数据进行回归。
更新日期:2017-12-10
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