Larger Spontaneous Polarization Ferroelectric Inorganic−Organic Hybrids: [PbI3]∞Chains Directed Organic Cations Aggregation to Kagomé-Shaped Tubular Architecture,Journal of the American Chemical Society

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Larger Spontaneous Polarization Ferroelectric Inorganic−Organic Hybrids: [PbI3]∞Chains Directed Organic Cations Aggregation to Kagomé-Shaped Tubular Architecture
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2010-01-13 , DOI: 10.1021/ja907562m
Hai-Rong Zhao ₁ , Dong-Ping Li ₁ , Xiao-Ming Ren ₁ , You Song ₁ , Wan-Qin Jin ₁

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Four isostructural inorganic-organic hybrid ferroelectric compounds, assembled from achiral 3-R-benzylidene-1-aminopyridiniums (R = NO(2), Br, Cl, or F for 1-4, respectively) and [PbI(3)](-) anions with the chiral Kagomé-shaped tubular aggregating architecture, show larger spontaneous polarizations.

中文翻译：

更大的自发极化铁电无机-有机杂化物：[PbI3]∞链定向有机阳离子聚集到 Kagomé 形管状结构

四种同构无机-有机杂化铁电化合物，由非手性 3-R-苯亚甲基-1-氨基吡啶鎓（R = NO(2)、Br、Cl 或 F 分别代表 1-4）和 [PbI(3)]( -) 具有手性 Kagomé 形管状聚集结构的阴离子，显示出更大的自发极化。

更新日期：2010-01-13

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