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Spherical Aggregates and Crystal Structure of Naphthalenediimide-Based Macrocycle and Complexation with Perylene
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2017-11-30 00:00:00 , DOI: 10.1021/acs.cgd.7b01361 Masahide Tominaga 1 , Masatoshi Kawahata 1 , Tsutomu Itoh 2 , Kentaro Yamaguchi 1
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2017-11-30 00:00:00 , DOI: 10.1021/acs.cgd.7b01361 Masahide Tominaga 1 , Masatoshi Kawahata 1 , Tsutomu Itoh 2 , Kentaro Yamaguchi 1
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A naphthalenediimide-based macrocycle with adamantane parts was synthesized from naphthalenetetracarboxylic dianhydride and 1,3-adamantanedimethanamine. The addition of methanol to a chloroform solution of the macrocycle led to formation of spherical species and their fused network aggregates, which were transformed into crystals. X-ray analysis showed a crescent-shaped molecular structure. In the presence of perylene, charge-transfer co-crystals of sandwich-type complexes were generated via self-assembly of nanostructures.
中文翻译：
萘二酰亚胺基大环的球形聚集体和晶体结构及与and的络合
由萘四甲酸二酐和1，3-金刚烷二甲胺合成了具有金刚烷部分的萘二甲酰亚胺基大环化合物。在大环的氯仿溶液中添加甲醇会导致形成球形物质及其稠合的网络聚集体，然后将其转变为晶体。X射线分析显示新月形分子结构。在per存在下，通过纳米结构的自组装产生了夹心型复合物的电荷转移共晶体。
更新日期：2017-11-30
中文翻译：
萘二酰亚胺基大环的球形聚集体和晶体结构及与and的络合
由萘四甲酸二酐和1，3-金刚烷二甲胺合成了具有金刚烷部分的萘二甲酰亚胺基大环化合物。在大环的氯仿溶液中添加甲醇会导致形成球形物质及其稠合的网络聚集体，然后将其转变为晶体。X射线分析显示新月形分子结构。在per存在下，通过纳米结构的自组装产生了夹心型复合物的电荷转移共晶体。
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