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Selective Oxidative Decarboxylation of Amino Acids to Produce Industrially Relevant Nitriles by Vanadium Chloroperoxidase
ChemSusChem ( IF 7.5 ) Pub Date : 2012-05-03 , DOI: 10.1002/cssc.201200098 Andrada But , Jérôme Le Nôtre , Elinor L. Scott , Ron Wever , Johan P. M. Sanders
ChemSusChem ( IF 7.5 ) Pub Date : 2012-05-03 , DOI: 10.1002/cssc.201200098 Andrada But , Jérôme Le Nôtre , Elinor L. Scott , Ron Wever , Johan P. M. Sanders
Industrial nitriles from biomass: Vanadium‐chloroperoxidase is successfully used to transform selectively glutamic acid into 3‐cyanopropanoic acid, a key intermediate for the synthesis of bio‐succinonitrile and bio‐acrylonitrile, by using a catalytic amount of a halide salt. This clean oxidative decarboxylation can be applied to mixtures of amino acids obtained from plant waste streams, leading to easily separable nitriles.
中文翻译:
钒氯过氧化物酶对氨基酸进行选择性氧化脱羧以生产与工业相关的腈
来自生物质的工业腈:钒-氯过氧化物酶已成功用于通过催化量的卤化物盐将谷氨酸选择性地转化为3-氰基丙酸,3-氰基丙酸是合成生物琥珀腈和生物丙烯腈的关键中间体。这种清洁的氧化脱羧作用可应用于从植物废物流中获得的氨基酸混合物,从而导致腈易于分离。
更新日期:2012-05-03
![image image](https://wol-prod-cdn.literatumonline.com/cms/attachment/d6bf7b4f-8f37-4675-9fc4-c9e728cafeb1/mcontent.gif)
中文翻译:
![](https://scdn.x-mol.com/jcss/images/paperTranslation.png)
钒氯过氧化物酶对氨基酸进行选择性氧化脱羧以生产与工业相关的腈
来自生物质的工业腈:钒-氯过氧化物酶已成功用于通过催化量的卤化物盐将谷氨酸选择性地转化为3-氰基丙酸,3-氰基丙酸是合成生物琥珀腈和生物丙烯腈的关键中间体。这种清洁的氧化脱羧作用可应用于从植物废物流中获得的氨基酸混合物,从而导致腈易于分离。
![图像 图像](https://wol-prod-cdn.literatumonline.com/cms/attachment/d6bf7b4f-8f37-4675-9fc4-c9e728cafeb1/mcontent.gif)