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EnantiopureC1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2012-03-06 , DOI: 10.1021/ja300503k Sebastien Monfette 1 , Zoë R. Turner 1 , Scott P. Semproni 1 , Paul J. Chirik 1
Journal of the American Chemical Society ( IF 14.4 ) Pub Date : 2012-03-06 , DOI: 10.1021/ja300503k Sebastien Monfette 1 , Zoë R. Turner 1 , Scott P. Semproni 1 , Paul J. Chirik 1
Affiliation
Enantiopure C(1)-symmetric bis(imino)pyridine cobalt chloride, methyl, hydride, and cyclometalated complexes have been synthesized and characterized. These complexes are active as catalysts for the enantioselective hydrogenation of geminal-disubstituted olefins.
中文翻译:
用于不对称烯烃氢化的 EnantiopureC1-对称双(亚氨基)吡啶钴配合物
Enantiopure C(1)-对称双(亚氨基)吡啶氯化钴、甲基、氢化物和环金属化配合物已合成和表征。这些配合物可作为对映选择性氢化的孪生二取代烯烃的催化剂。
更新日期:2012-03-06
中文翻译:
用于不对称烯烃氢化的 EnantiopureC1-对称双(亚氨基)吡啶钴配合物
Enantiopure C(1)-对称双(亚氨基)吡啶氯化钴、甲基、氢化物和环金属化配合物已合成和表征。这些配合物可作为对映选择性氢化的孪生二取代烯烃的催化剂。