Cycloparaphenylenes and related nanohoops,Chemical Society Reviews

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Cycloparaphenylenes and related nanohoops
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2015-03-04 00:00:00 , DOI: 10.1039/c4cs00366g
Simon E. Lewis _{1,

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Affiliation

The first synthesis of a cyclic oligophenylene possessing a radial π system was reported in 2008. In the short period that has elapsed since, there has been an ever-increasing level of interest in molecules of this type, as evidenced by the volume of publications in this area. This interest has been driven by the highly unusual properties of these molecules in comparison to their linear oligoarene analogues, as well as the diverse array of potential applications for them. Notably, CPPs and related structures were proposed as viable templates for the bottom-up synthesis of single-walled carbon nanotubes (SWCNTs), a proposition which has recently been realised. This review gives a comprehensive and strictly chronological (by date of first online publication) treatment of literature reports from the inception of the field, with emphasis on both synthesis and properties of CPPs and related nanohoops. (The scope of this review is restricted to molecules possessing a radial π system consisting entirely of subunits which are aromatic in isolation, e.g. CPPs, but not cycloparaphenyleneacetylenes or cyclopolyacetylenes).

中文翻译：

环对亚苯基及相关的纳米环

据报道，2008年首次合成了具有径向π系统的环状低聚亚苯基。自那以后的短时间内，人们对这种类型的分子的兴趣与日俱增，这一点在2002年的出版物中就可以看到。这片区域。与这些分子的线性低聚芳烃类似物相比，这些分子具有非常不寻常的特性，并且具有多种潜在的应用前景，从而引起了人们的兴趣。值得注意的是，CPPs和相关结构被提出作为自底向上合成单壁碳纳米管（SWCNTs）的可行模板，最近已经实现了这一主张。这篇评论从该领域的创立开始就对文献报告进行了全面，严格的时间顺序（按首次在线发布的日期），着重于CPP和相关纳米环的合成和性质。（这篇评论的范围仅限于具有径向π系统的分子，该系统完全由孤立的芳香族亚基组成，例如CPP，但不包括环对亚苯基乙炔或环聚乙炔）。

更新日期：2015-03-04

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