New porphyrin-based dendrimers with alkene linked fluorenyl antennae for optics†,New Journal of Chemistry

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New porphyrin-based dendrimers with alkene linked fluorenyl antennae for optics†
New Journal of Chemistry ( IF 2.7 ) Pub Date : 2017-11-16 00:00:00 , DOI: 10.1039/c7nj03522e
Dandan Yao _{1,

2,

3,

4,

5} , Xu Zhang _{1,

2,

3,

4,

5} , Seifallah Abid _{5,

6,

7,

8,

9} , Limiao Shi _{1,

2,

3,

4,

5} , Mireille Blanchard-Desce _{5,

10,

11,

12,

13} , Olivier Mongin _{1,

2,

3,

4,

5} , Frédéric Paul _{1,

2,

3,

4,

5} , Christine O. Paul-Roth _{1,

2,

3,

4,

5}

Affiliation

The design of porphyrin-based dendrimers featuring conjugated dendrons via alkene spacers herein demonstrates their important role in determining linear optical properties, as well as two-photon absorption (PA) and singlet oxygen photosensitising properties. Improvement in these properties compared to those observed for their analogous alkyne spacers makes these molecules appealing for combined 2-photon-based photodynamic therapy (PDT) and imaging.

中文翻译：

新的基于卟啉的树枝状大分子，带有烯烃连接的芴基触角，用于光学器件†

通过本文的经由间隔基的共轭树突为特征的基于卟啉的树状大分子的设计证明了它们在确定线性光学性质以及双光子吸收（PA）和单线态氧光敏性质中的重要作用。与观察到的类似炔间隔基相比，这些性质的改进使这些分子吸引了基于2光子的光动力疗法（PDT）和成像相结合的需求。

更新日期：2017-11-16

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