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Self‐Assembly of a Giant Tetrahedral 3 d–4 f Single‐Molecule Magnet within a Polyoxometalate System
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2015-09-22 , DOI: 10.1002/anie.201504663
Masooma Ibrahim , Valeriu Mereacre , Nicolas Leblanc , Wolfgang Wernsdorfer , Christopher E. Anson , Annie K. Powell

A giant tetrahedral heterometallic polyoxometalate (POM) [Dy30Co8Ge12W108O408(OH)42(OH2)30]56−, which shows single‐molecule magnet (SMM) behavior, is described. This hybrid contains the largest number of 4f ions of any polyoxometalate (POM) reported to date and is the first to incorporate two different 3d–4f and 4f coordination cluster assemblies within same POM framework.

中文翻译:

多金属氧酸盐系统中四面体3 d–4 f巨型单磁体的自组装

描述了一种巨大的四面体杂金属多金属氧酸盐(POM)[Dy 30 Co 8 Ge 12 W 108 O 408(OH)42(OH 230 ] 56-,它显示了单分子磁体(SMM)的行为。迄今为止,该杂化剂包含的多金属氧酸盐(POM)中4f离子的数量最多,并且是第一个在相同的POM框架中合并两个不同的3d–4f和4f配位簇组件的化合物。
更新日期:2015-09-22
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