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Cover Feature: A One‐Step Germole to Silole Transformation and a Stable Isomer of a Disilabenzene (Chem. Eur. J. 4/2018)
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-11-02 , DOI: 10.1002/chem.201704980 Crispin R. W. Reinhold 1 , Zhaowen Dong 1 , Jan M. Winkler 1 , Henning Steinert 1 , Marc Schmidtmann 1 , Thomas Müller 1
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-11-02 , DOI: 10.1002/chem.201704980 Crispin R. W. Reinhold 1 , Zhaowen Dong 1 , Jan M. Winkler 1 , Henning Steinert 1 , Marc Schmidtmann 1 , Thomas Müller 1
Affiliation
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An unprecedented germole to silole transformation opened the way for the synthesis of novel silylenes based on a bicyclohexene skeleton, so‐called BCH silylenes. The astonishing stability of BCH silylenes results from homoconjugation between the dicoordinated Si atom and a remote C=C bond. This stabilization is more efficient than conventional electron delocalization, indicated by the fact that BCH silylenes are stable derivatives of the global minimum of the C4Si2H6 potential energy surface. More information can be found in the Full Paper by T. Müller et al. on page 848.
中文翻译：
封面功能：一步Germole到Silole的转化和二硅苯的稳定异构体（Chem.Eur.J.4 / 2018）
前所未有的从胚芽到硅烷的转化为基于双环己烯骨架的新型甲硅烷基，即所谓的BCH甲硅烷基的合成开辟了道路。BCH甲硅烷基的惊人稳定性源于双配位Si原子与远端C = C键之间的均共轭作用。这种稳定比常规电子离域更有效，这一事实表明BCH甲硅烷基是C 4 Si 2 H 6势能面整体最小值的稳定衍生物。可以在T.Müller等人的论文全文中找到更多信息。在第848页。
更新日期：2017-11-02
中文翻译：
封面功能：一步Germole到Silole的转化和二硅苯的稳定异构体（Chem.Eur.J.4 / 2018）
前所未有的从胚芽到硅烷的转化为基于双环己烯骨架的新型甲硅烷基，即所谓的BCH甲硅烷基的合成开辟了道路。BCH甲硅烷基的惊人稳定性源于双配位Si原子与远端C = C键之间的均共轭作用。这种稳定比常规电子离域更有效，这一事实表明BCH甲硅烷基是C 4 Si 2 H 6势能面整体最小值的稳定衍生物。可以在T.Müller等人的论文全文中找到更多信息。在第848页。
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