Linear and Third-Order Nonlinear Optical Properties of Triazobenzene-1,3,5-triazinane-2,4,6-trione (Isocyanurate) Derivatives.,ChemPlusChem

当前位置： X-MOL 学术 › ChemPlusChem › 论文详情

Our official English website, www.x-mol.net, welcomes your feedback! (Note: you will need to create a separate account there.)

Linear and Third-Order Nonlinear Optical Properties of Triazobenzene-1,3,5-triazinane-2,4,6-trione (Isocyanurate) Derivatives.
ChemPlusChem ( IF 3.0 ) Pub Date : 2017-12-04 , DOI: 10.1002/cplu.201700396
Ziemowit Pokladek _{1,

2} , Marta Dudek _{1,

2} , Olivier Mongin ₃ , Rémi Métivier ₄ , Piotr Mlynarz ₁ , Marek Samoc ₂ , Katarzyna Matczyszyn ₂ , Frédéric Paul ₃

Affiliation

The synthesis of three new isocyanurate derivatives 2-X (X=NO2 , H, NMe2 ) with azobenzene arms terminated by various X substituents is reported, and their linear and nonlinear absorption properties are studied. It is shown that mixtures that contain increased contents of cis-azo isomers can be reversibly generated upon photoirradiation at specific wavelengths from the most stable all-trans isomers with X=NO2 and H. In addition, we show that 2-X derivatives are two-photon absorbers with cross-section maxima around 120 GM for 2-NO2 , thus indicating that trans-to-cis isomerization might be achievable by two-photon excitation, whereas the photoinduced structural changes should have only a modest influence on these nonlinear absorption properties.

中文翻译：

三偶氮苯-1,3,5-三嗪烷-2,4,6-三酮（异氰脲酸酯）衍生物的线性和三阶非线性光学性质。

报道了三种新的异氰脲酸酯衍生物2-X（X = NO2，H，NMe2）的合成，该衍生物的偶氮苯臂被多个X取代基封端，并研究了它们的线性和非线性吸收特性。结果表明，在特定波长下，由X = NO2和H组成的最稳定的全反式异构体，在特定波长下进行光辐照时，可逆生成顺式偶氮异构体含量增加的混合物。此外，我们表明2-X衍生物是两种-NO2的横截面最大值约为120 GM的-光子吸收剂，因此表明通过双光子激发可以实现反式-顺式异构化，而光诱导的结构变化对这些非线性吸收性质的影响应该很小。

更新日期：2017-12-04

点击分享查看原文

点击收藏

阅读更多本刊新发论文本刊介绍/投稿指南