A microporous MOF with open metal sites and Lewis basic sites for selective CO2 capture,Dalton Transactions

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A microporous MOF with open metal sites and Lewis basic sites for selective CO2 capture
Dalton Transactions ( IF 3.5 ) Pub Date : 2017-10-02 00:00:00 , DOI: 10.1039/c7dt03255b
Jinjie Qian _{1,

2,

3,

4} , Qipeng Li _{4,

5,

6,

7} , Linfeng Liang _{8,

9,

10,

11,

12} , Ting-Ting Li _{4,

13,

14,

15} , Yue Hu _{1,

2,

3,

4} , Shaoming Huang _{1,

2,

3,

4}

Affiliation

A robust indium–organic framework (InOF-15) with open metal sites and Lewis basic sites has been successfully synthesized using a quinoline-based dicarboxylic acid. Moreover, it exhibits high IAST selective CO₂ sorption from CO₂/CH₄ and CO₂/N₂ mixtures at 273 K, which has been attributed to the coexistence of OMSs and LBSs with strong synergistic effects.

中文翻译：

具有开放金属位点和Lewis碱性位点以选择性捕获CO _2的微孔MOF

使用基于喹啉的二羧酸已成功合成了具有开放金属位点和Lewis碱性位点的坚固的铟有机骨架（InOF-15）。而且，它在273 K时从CO ₂ / CH ₄和CO ₂ / N ₂混合物中表现出很高的IAST选择性CO ₂吸附能力，这归因于OMS和LBS并存，具有很强的协同作用。

更新日期：2017-10-24

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