当前位置：
X-MOL 学术
›
Cryst. Growth Des.
›
论文详情
Our official English website, www.x-mol.net, welcomes your
feedback! (Note: you will need to create a separate account there.)
Highly Interpenetrated Robust Microporous Hydrogen-Bonded Organic Framework for Gas Separation
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2017-10-23 00:00:00 , DOI: 10.1021/acs.cgd.7b01322 Wei Yang 1 , Jiawei Wang 2 , Hailong Wang 1 , Zongbi Bao 1, 2 , John Cong-Gui Zhao 1 , Banglin Chen 1
Crystal Growth & Design ( IF 3.2 ) Pub Date : 2017-10-23 00:00:00 , DOI: 10.1021/acs.cgd.7b01322 Wei Yang 1 , Jiawei Wang 2 , Hailong Wang 1 , Zongbi Bao 1, 2 , John Cong-Gui Zhao 1 , Banglin Chen 1
Affiliation
|
A hydrogen-bonded organic framework (HOF), HOF-11, has been successfully prepared by the slow diffusion of hexane into a tetrahydrofuran solution of tris(4-carboxyphenyl)amine (TCPA). HOF-11 has been characterized by single-crystal and powder X-ray diffraction analysis, which is composed of TCPA ligands connected by the intermolecular hydrogen-bonding interactions in the carboxylic group dimer, showing 11-fold interpenetrated three-dimensional hydrogen-bonded networks in a (10,3)-b topology with the pore size of 6.2 × 6.8 Å2. The permanent porosity of degassed HOF was demonstrated by virtue of the CO2 sorption and selective gas adsorption.
中文翻译：
高度互穿的鲁棒微孔氢键结合有机骨架，用于气体分离
通过将己烷缓慢扩散到三（4-羧苯基）胺（TCPA）的四氢呋喃溶液中，已成功制备了氢键键合的有机骨架（HOF-11）。HOF-11已通过单晶和粉末X射线衍射分析进行了表征，它由通过羧基二聚体中的分子间氢键相互作用连接的TCPA配体组成，显示出11倍互穿的三维氢键网络在用6.2×6.8埃的孔径的（10,3）-b拓扑2。通过CO 2吸附和选择性气体吸附证明了脱气HOF的永久孔隙率。
更新日期：2017-10-23
中文翻译：
高度互穿的鲁棒微孔氢键结合有机骨架，用于气体分离
通过将己烷缓慢扩散到三（4-羧苯基）胺（TCPA）的四氢呋喃溶液中，已成功制备了氢键键合的有机骨架（HOF-11）。HOF-11已通过单晶和粉末X射线衍射分析进行了表征，它由通过羧基二聚体中的分子间氢键相互作用连接的TCPA配体组成，显示出11倍互穿的三维氢键网络在用6.2×6.8埃的孔径的（10,3）-b拓扑2。通过CO 2吸附和选择性气体吸附证明了脱气HOF的永久孔隙率。
京公网安备 11010802027423号