Frontispiece: Indole- and Pyrrole-BX: Bench-Stable Hypervalent Iodine Reagents for Heterocycle Umpolung,Chemistry - A European Journal

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Frontispiece: Indole- and Pyrrole-BX: Bench-Stable Hypervalent Iodine Reagents for Heterocycle Umpolung
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-10-20 02:28:49 , DOI: 10.1002/chem.201785963
Paola Caramenti ₁ , Stefano Nicolai ₁ , Jerome Waser ₁

Affiliation

Electrophilic Indoles/Pyrroles: The first synthesis of indole- and pyrrole-derived benziodoxole reagents is reported in one step from the heterocycles. The new Indole- and Pyrrole-BX reagents are stable up to 150 °C. They can be used as electrophilic partners for selective heterocycle transfer onto the C−H bonds of arenes ortho to directing groups with rhodium or ruthenium catalysts. For more information see the Communication by J. Waser et al. on page 14702 ff.

中文翻译：

代表作：Indole-和Pyrrrole-BX：适用于杂环Umpolung的台式稳定的高价碘试剂

亲电子吲哚/吡咯：吲哚和吡咯衍生的苯并吲哚酚试剂的第一次合成是从杂环一步而来的。新型Indole-和Pyrrole-BX试剂可在高达150°C的温度下稳定。的芳烃它们可以用作用于选择性杂环转印到C-H键的亲电子伙伴邻位到定位基团与铑或钌的催化剂。有关更多信息，请参见J. Waser等人的《通信》。在14702页上ff。

更新日期：2017-10-20

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