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Ru(bpy)3Cl2 as a Photocatalyst for Visible-Light-Induced Fluoroalkylation of Anilines with BrCF2CF2Br: A Facile Route to 2-Bromo-1,1,2,2-tetrafluoroethyl Arenes
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-10-19 06:30:35 , DOI: 10.1002/ajoc.201700422 Jingjing Kong 1 , Jianfang Jiang 1 , Yang Huang 1 , Yue-Guang Lou 1 , Xiao-Fei Li 1 , Chun-Yang He 1
Asian Journal of Organic Chemistry ( IF 2.8 ) Pub Date : 2017-10-19 06:30:35 , DOI: 10.1002/ajoc.201700422 Jingjing Kong 1 , Jianfang Jiang 1 , Yang Huang 1 , Yue-Guang Lou 1 , Xiao-Fei Li 1 , Chun-Yang He 1
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Readily available: A convenient method for the preparation of 2-bromo-1,1,2,2-tetrafluoroethyl arenes, using commercially available anilines and BrCF2CF2Br as starting materials is described. The reaction is highly efficient and proceeds under the blue-LED irradiation, enabling the installation of amino and fluoroalkyl moieties.
中文翻译：
Ru（bpy）3Cl2作为可见光诱导苯胺与BrCF2CF2Br的氟代烷基化的光催化剂：通往2-Bromo-1,1,2,2-四氟乙基芳烃的简便途径
易于获得：描述了一种使用市售苯胺和BrCF 2 CF 2 Br作为起始原料制备2-溴-1,1,2,2-四氟乙基芳烃的简便方法。该反应是高效的，并且在蓝光LED照射下进行，从而能够安装氨基和氟代烷基部分。
更新日期：2017-10-19
中文翻译：
Ru（bpy）3Cl2作为可见光诱导苯胺与BrCF2CF2Br的氟代烷基化的光催化剂：通往2-Bromo-1,1,2,2-四氟乙基芳烃的简便途径
易于获得：描述了一种使用市售苯胺和BrCF 2 CF 2 Br作为起始原料制备2-溴-1,1,2,2-四氟乙基芳烃的简便方法。该反应是高效的，并且在蓝光LED照射下进行，从而能够安装氨基和氟代烷基部分。
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