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Concentrated Aqueous Sodium Tosylate as Green Medium for Alkene Oxidation and Nucleophilic Substitution Reactions
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2017-10-18 00:00:00 , DOI: 10.1021/acs.joc.7b01679
Tal Sela 1 , Xiaoxi Lin 1 , Arkadi Vigalok 1
Affiliation  

A hydrotropic solution of highly concentrated sodium tosylate (NaOTs) can be used as a recyclable medium for the environmentally benign oxidation of conjugated alkenes with H2O2. Both uncatalyzed and metal-catalyzed reactions provided the corresponding oxidation products in higher yields than in pure water or many common organic solvents.

中文翻译:

浓缩甲苯磺酸钠作为烯烃氧化和亲核取代反应的绿色介质

可以使用高浓度甲苯磺酸钠(NaOTs)的水溶溶液作为可循环介质,以H 2 O 2对共轭烯烃进行环境友好的氧化。与在纯水或许多常见有机溶剂中相比,未催化反应和金属催化反应均能以更高的产率提供相应的氧化产物。
更新日期:2017-10-18
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