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η1-Arene Complexes as Intermediates in the Preparation of Molecular Phosphorescent Iridium(III) Complexes
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-10-16 06:45:37 , DOI: 10.1002/chem.201703252
Miguel A. Esteruelas 1 , Daniel Gómez-Bautista 1 , Ana M. López 1 , Enrique Oñate 1 , Jui-Yi Tsai 2 , Chuanjun Xia 2
Affiliation  

Green phosphorescence: Molecular phosphorescent heteroleptic bis-tridentate iridium(III) complexes with a six-membered heterometallacycle in their structure (see figure) have been prepared via η1-arene intermediates. They are green emitters that display short lifetimes (110 μs) and high quantum yields (0.73–0.87) in the solid state.

中文翻译:

η1-芳烃配合物在制备分子磷铱(III)配合物中的中间体

绿色磷光:分子磷光杂双-三齿铱(III)配合物在其结构中的六元heterometallacycle(见图)已经通过η制备1个-arene中间体。它们是绿色的发射器,在固态时显示出短寿命(1 10μs)和高量子产率(0.73–0.87)。
更新日期:2017-10-16
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