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Measurement and Correlation of the Solubility of Sodium 2-Chlorotoluene-4-sulfonate in Selected Pure Solvents and Aqueous Organic Solutions
Journal of Chemical & Engineering Data ( IF 2.0 ) Pub Date : January 19, 2016 , DOI: 10.1021/acs.jced.5b00655
Shi-Liang Liu 1 , Hai-Ming Li 1 , Guang Han 1 , Yuan-Xiao Li 1 , Guo-Liang Zhang 1 , Feng-Bao Zhang 1 , Qing Xia 1
Affiliation  

The solubilities of the sodium 2-chlorotoluene-4-sulfonate (CTSNa) in water, methanol, formic acid, dimethyl sulfoxide (DMSO), N,N-dimethylformamide (DMF), binary (methanol + water) mixed solvents, and binary (ethanol + water) mixed solvents were determined experimentally over the temperature range from (280 to 335) K at atmospheric pressure using a dynamic method. The mole fraction of water in the two solvent mixtures ranged from 0.0000 to 1.0000 and 0.2006 to 1.0000, respectively. A synergistic effect on CTSNa solubility was observed with the maximum solubility at solute-free mole fraction of ethanol x20 = 0.2082 and solute-free mole fraction of methanol x30 = 0.3985, respectively. The solubility data were correlated with the thermodynamic electrolyte nonrandom two-liquid (E-NRTL) model and the root-mean-square deviations of solubility temperature varied from (0.24 to 1.10) K.

中文翻译:

2-氯甲苯-4-磺酸钠在纯溶剂和有机水溶液中的溶解度的测量和相关性

2-氯甲苯-4-磺酸钠(CTSNa)在水,甲醇,甲酸,二甲基亚砜(DMSO),NN-二甲基甲酰胺(DMF),二元(甲醇+水)混合溶剂和二元(使用动态方法,在大气压下(280至335)K的温度范围内,通过实验确定了乙醇+水)混合溶剂。两种溶剂混合物中水的摩尔分数分别为0.0000至1.0000和0.2006至1.0000。在乙醇的无溶质摩尔分数x 2 0 = 0.2082和甲醇的无溶质摩尔分数x 3 0时,观察到了对CTSNa溶解度的协同作用。分别为0.3985。溶解度数据与热力学电解质非随机两液(E-NRTL)模型相关,溶解度温度的均方根偏差在(0.24至1.10)K之间变化。
更新日期:2017-01-31
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