Synthesis of Spiro[2.5]octa-4,7-dien-6-one with Consecutive Quarternary Centers via 1,6-Conjugate Addition Induced Dearomatization of para-Quinone Methides,Chemical Communications

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Synthesis of Spiro[2.5]octa-4,7-dien-6-one with Consecutive Quarternary Centers via 1,6-Conjugate Addition Induced Dearomatization of para-Quinone Methides
Chemical Communications ( IF 4.3 ) Pub Date : 2015-09-04 00:00:00 , DOI: 10.1039/c5cc06287j
Kuo Gai _{1,

2,

3,

4,

5} , Xinxin Fang _{1,

2,

3,

4,

5} , Xuanyi Li _{1,

2,

3,

4,

5} , Jinyi Xu _{1,

2,

3,

4,

5} , Xiaoming Wu _{1,

2,

3,

4,

5} , Aijun Lin _{1,

2,

3,

4,

5} , Hequan Yao _{1,

2,

3,

4,

5}

Affiliation

An efficient one-pot approach for the synthesis of spiro[2.5]octa-4,7-dien-6-ones by employing para-quinone methides has been developed. The reaction proceeded smoothly in high yields under mild conditions without the use of...

中文翻译：

1,6-共轭加成诱导对位醌甲基脱芳香化反应合成具有连续四元中心的Spiro [2.5] octa-4,7-dien-6-one

已经开发出一种有效的一锅法，该方法通过使用对醌甲基化物来合成螺[2.5] octa-4,7-dien-6-one。在温和条件下，不使用...即可使反应平稳，高产率地进行。

更新日期：2015-09-06

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