Borane-Stabilized Isomeric Dimers of the Phosphaethynolate Anion,Angewandte Chemie International Edition

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Borane-Stabilized Isomeric Dimers of the Phosphaethynolate Anion
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-10-04 12:12:01 , DOI: 10.1002/anie.201708646
Kevin M. Szkop ₁ , Andrew R. Jupp ₁ , Riccardo Suter ₂ , Hansjörg Grützmacher ₂ , Douglas W. Stephan ₁

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When two become one: The phosphaethynolate anion ([PCO]⁻) can interact with different boranes through the O or P terminus to give transient monomeric species. The Lewis acids mediate and stabilize the subsequent dimerization to give constitutional isomers of stable dimers (see scheme).

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