The Zn atom in dichloro[(3,5-dimethyl-1H-pyrazol-1-yl)methane]zinc(II), [ZnCl2(C11H16N4)], (I), is tetrahedrally coordinated by two N atoms from one bis(3,5-dimethylpyrazolyl)methane ligand and two terminal Cl atoms. The molecule has no crystallographic symmetry. One H atom of the CH2 group of the bis(3,5-dimethylpyrazolyl)methane ligand interacts with a Cl atom of an adjacent molecule to yield intermolecular C-H...Cl contacts, thereby forming a one-dimensional zigzag chain extending along the b axis. On the other hand, in di-mu-chloro-bis{chloro[(3,5-dimethyl-1H-pyrazol-1-yl)methane]cadmium(II)}, [Cd2Cl4(C11H16N4)2], (II), each of the two crystallographically equivalent Cd atoms is pentacoordinated by two N atoms from one bis(3,5-dimethylpyrazolyl)methane ligand, and by one terminal and two bridging Cl- anions. The molecule has a crystallographic centre of symmetry located at the mid-point of the Cd...Cd line. One H atom of the CH2 group of the bis(3,5-dimethylpyrazolyl)methane ligand interacts with a Cl atom of an adjacent molecule to produce pairwise intermolecular C-H...Cl contacts, thereby affording chains of molecules running along the c axis.

中文翻译：

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二氯[（3,5-二甲基-1H-吡唑-1-基）甲烷]锌（II）和二亩-氯-双{氯[（3,5-二甲基-1H-吡唑-1-基）甲烷]镉（II）}。

二氯[（3,5-二甲基-1H-吡唑-1-基）甲烷]锌（II），[ZnCl2（C11H16N4）]（I）中的锌原子与来自一个双（ 3，5-二甲基吡唑基）甲烷配体和两个末端Cl原子。该分子没有晶体学对称性。双（3,5-二甲基吡唑基）甲烷配体的CH2基团的一个H原子与相邻分子的Cl原子相互作用以产生分子间CH ... Cl接触，从而形成沿b延伸的一维之字形链轴。另一方面，在二-氯-双{氯[（3,5-二甲基-1H-吡唑-1-基）甲烷]镉（II）}中，[Cd2Cl4（C11H16N4）2]，（II） ，两个晶体学上等效的Cd原子中的每一个都被一个双（3,5-二甲基吡唑基）甲烷配体中的两个N原子，一个末端和两个桥连的Cl-阴离子配位。该分子的晶体学对称中心位于Cd ... Cd线的中点。双（3,5-二甲基吡唑基）甲烷配体的CH2基团的一个H原子与相邻分子的Cl原子相互作用以产生成对的分子间CH ... Cl接触，从而提供沿c轴延伸的分子链。