Supramolecular Host–Guest Inclusion for Distinguishing Cucurbit[7]uril-Based Pseudorotaxanes from Small-Molecule Ligands in Coordination Assembly with a Uranyl Center,Chemistry - A European Journal

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Supramolecular Host–Guest Inclusion for Distinguishing Cucurbit[7]uril-Based Pseudorotaxanes from Small-Molecule Ligands in Coordination Assembly with a Uranyl Center
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-09-08 05:10:58 , DOI: 10.1002/chem.201702752
Lei Mei ₁ , Zhen-Ni Xie ₁ , Kong-qiu Hu ₁ , Li-Yong Yuan ₁ , Zeng-Qiang Gao ₂ , Zhi-Fang Chai _{1,

3} , Wei-Qun Shi ₁

Affiliation

Beyond small-molecule-based coordination assembly: Bulky cucurbit[7]uril macrocycle exerts significant influence on the groups of the guest ligand threading in it, and achieves structural diversity of as-generated uranyl compounds by combined effects of improved stability and increased steric hindrance for the cucurbit[7]uril-encapsulated pseudorotaxane linker.

中文翻译：

超分子宿主-客体包合物用于区分小分子配体与铀酰中心配位的基于葫芦[7]尿嘧啶的假轮烷。

超越基于小分子的配位体：庞大的葫芦[7]尿嘧啶大环对其客体配体的基团产生重大影响，并通过提高稳定性和增加空间位阻的综合作用实现了生成的铀酰化合物的结构多样性用于葫芦丝[7]包裹尿嘧啶的假轮烷接头。

更新日期：2017-09-08

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