Isocyanurate Formation During Oxazolidinone Synthesis from Epoxides and Isocyanates Catalysed by a Chromium(Salphen) Complex,Chemistry - A European Journal

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Isocyanurate Formation During Oxazolidinone Synthesis from Epoxides and Isocyanates Catalysed by a Chromium(Salphen) Complex
Chemistry - A European Journal ( IF 3.9 ) Pub Date : 2017-08-18 01:30:25 , DOI: 10.1002/chem.201702948
Xiao Wu ₁ , Jess Mason ₁ , Michael North ₁

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A tale of two reactions: A chromimium(salphen) complex catalyses the formation of oxazolidinones from epoxides and isocyanates. However, with particularly electron-deficient isocyanates, the complex catalyses cyclotrimerisation of the isocyanate to an isocyanurate instead (see scheme).

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