Palladium complexes of 1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane were prepared and characterized with Pd[1,3,5,7-tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane]₂·dba shown to be an effective catalyst for use in the Suzuki and Sonogashira reactions and the α-arylation of ketones. Couplings using this versatile complex proceeded in excellent yields under mild conditions.

中文翻译：

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1,3,5,7-四甲基-2,4,8-三氧杂-6-苯基-6-磷金刚烷的钯配合物：铃木和Sonogashira反应的合成，晶体结构和用途以及酮的α-芳基化

制备了1,3,5,7-四甲基-2,4,8-三氧杂-6-苯基-6-磷金刚烷的钯配合物并用Pd [1,3,5,7-四甲基-2,4,8进行了表征[-trioxa-6-苯基-6-磷酸金刚烷] ₂ ·dba被证明是用于Suzuki和Sonogashira反应以及酮的α-芳基化反应的有效催化剂。使用这种多功能复合物的偶联在温和条件下以优异的产率进行。