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Total synthesis of 10-norparvulenone and of O-methylasparvenone using a xanthate-mediated free radical addition-cyclization sequence.
Organic Letters ( IF 4.9 ) Pub Date : 2003 Oct 2 , DOI: 10.1021/ol035394o
Alejandro Cordero Vargas 1 , Béatrice Quiclet-Sire 1 , Samir Z. Zard 1
Affiliation  

[reaction: see text] A short synthesis of (+/-)-10-norparvulenone and (+/-)-O-methylasparvenone was developed starting from commercially available m-methoxyphenol, hinging on a xanthate-mediated addition-cyclization sequence for the construction of the alpha-tetralone subunit.

中文翻译:

使用黄药介导的自由基加成环化序列进行10-去甲戊烯酮和O-甲基天冬酰胺的全合成。

[反应:见正文]从可商购的间甲氧基苯酚开始,开发了由(x)的黄原酸酯介导的加成环化序列,合成(+/-)-10-去甲戊烯酮和(+/-)-O-甲基天冬酰胺的简短合成方法。 α-四氢萘酮亚基的构建。
更新日期:2017-01-31
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