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Highly efficient synthesis of O-(2,4-dinitrophenyl)hydroxylamine. Application to the synthesis of substituted N-benzoyliminopyridinium ylides.
The Journal of Organic Chemistry ( IF 3.3 ) Pub Date : 2003 Sep 5 , DOI: 10.1021/jo034456l
Claude Legault 1 , André B. Charette 1
Affiliation  

An efficient two-step synthesis of O-(2,4-dinitrophenyl)hydroxylamine is described along with a comparison of its aminating efficiency with O-mesitylenesulfonylhydroxylamine (MSH). It was used in an expedient N-amination/benzoylation procedure involving various substituted pyridines, leading to polysubstituted N-benzoyliminopyridinium ylides, and the scope of its amination power was studied.

中文翻译:

O-(2,4-二硝基苯基)羟胺的高效合成。在合成取代的N-苯甲酰亚氨基吡啶鎓盐中的应用。

描述了一种有效的两步合成O-(2,4-二硝基苯基)羟胺的方法,并比较了其与O-次甲基亚磺酰基羟胺(MSH)的胺化效率。它被用于方便的N-氨基化/苯甲酰化过程,涉及各种取代的吡啶,导致多取代的N-苯并亚氨基吡啶基吡啶化,并研究了其胺化能力的范围。
更新日期:2017-01-31
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