A palladium‐catalyzed enantioselective CH arylation of N‐(o‐bromoaryl)‐diarylphosphinic amides is described for the synthesis of phosphorus compounds bearing a P‐stereogenic center. The method provides good enantioselectivities and high yields. The products were readily transformed into P‐chiral biphenyl monophosphine ligands.

中文翻译：

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钯催化的不对称Ç ？H-丙烯酸酯化反应，用于合成对立体异构化合物

钯催化对映选择性Ç  H的芳基化ñ - （ö -bromoaryl）-diarylphosphinic酰胺为磷化合物带有P-立体中心的合成中所述。该方法提供了良好的对映选择性和高产率。产物很容易转化为对映异构的手性联苯单膦配体。