The organomercurial compounds Hg[1-C(6)H(4)-2-C(H)=NC(6)H(5-n)R(n)](2) (R = 4-NMe(2), 6a; 4-Me, 6b; 4-I, 6c; 4-NO(2), 6d; 2-(i)Pr, 6e; 2-Me, 6f; 2,6-(i)Pr(2), 6g; 2,6-Me(2), 6h) have been prepared in good overall yield from 2-bromobenzaldehyde. All of the compounds have been characterized by elemental analysis, (1)H NMR, (13)C[(1)H] NMR, and infrared spectroscopy. In addition, compounds 6a [C(30)H(30)HgN(4), triclinic, P, a = 6.20000(10) A, b = 9.2315(2) A, c = 10.9069(3) A, alpha = 85.8510(10) degrees, beta = 89.3570(10) degrees, gamma = 87.206(2) degrees, Z = 1], 6b [C(28)H(24)HgN(2), monoclinic, P2(1)/c, a = 12.8260(5) A, b = 14.0675(4) A, c = 6.1032(2) A, beta = 90.0990(10) degrees, Z = 2], 6g [C(38)H(44)HgN(2), triclinic, P, a = 8.2626(2) A, b = 9.8317(2) A, c = 11.8873(3) A, alpha = 103.6650(10) degrees, beta = 109.3350(10) degrees, gamma = 104.627(2) degrees, Z = 1], and 6h [C(30)H(28)HgN(2), monoclinic, P2(1)/c, a = 12.5307(2) A, b = 10.9852(2) A, c = 18.2112(2) A, beta = 104.0190(10) degrees, gamma = 87.206(2) degrees, Z = 4] have been characterized by low-temperature single-crystal X-ray diffraction studies, and two different molecular geometries about the central mercury atom have been observed; intramolecular contacts suggest a van der Waals radius for Hg of 2.1-2.2 A.

中文翻译：

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Hg [1-C（6）H（4）-2-C（H）= NC（6）H（5-n）R（n）]（2）类型化合物的合成和表征。

有机汞化合物Hg [1-C（6）H（4）-2-C（H）= NC（6）H（5-n）R（n）]（2）（R = 4-NMe（2） ，6a; 4-Me，6b; 4-I，6c; 4-NO（2），6d; 2-（i）Pr，6e; 2-Me，6f; 2,6-（i）Pr（2） ，6g； 2,6-Me（2），6h）已由2-溴苯甲醛以较高的总收率制备。所有化合物均已通过元素分析，（1）H NMR，（13）C [（1）H] NMR和红外光谱进行了表征。此外，化合物6a [C（30）H（30）HgN（4），三斜晶系，P，a = 6.20000（10）A，b = 9.2315（2）A，c = 10.9069（3）A，alpha = 85.8510 （10）度，β= 89.3570（10）度，γ= 87.206（2）度，Z = 1]，6b [C（28）H（24）HgN（2），单斜度，P2（1）/ c， a = 12.8260（5）A，b = 14.0675（4）A，c = 6.1032（2）A，β= 90.0990（10）度，Z = 2]，6g [C（38）H（44）HgN（2） ），三斜度，P，a = 8.2626（2）A，b = 9.8317（2）A，c = 11.8873（3）A，alpha = 103.6650（10）度，beta = 109.3350（10）度，γ= 104.627（2）度，Z = 1]和6h [C（30）H（28）HgN（2），单斜晶，P2（1）/ c，a = 12.5307（2）A，b = 10.9852（ 2）A，c = 18.2112（2）A，β= 104.0190（10）度，γ= 87.206（2）度，Z = 4]已通过低温单晶X射线衍射研究进行了表征，其中两个已经观察到关于中心汞原子的不同分子几何结构；分子内接触表明Hg的范德华半径为2.1-2.2 A.