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Navigating the Chiral Pool in the Total Synthesis of Complex Terpene Natural Products
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-03-15 00:00:00 , DOI: 10.1021/acs.chemrev.6b00834 Zachary G. Brill 1 , Matthew L. Condakes 1 , Chi P. Ting 1 , Thomas J. Maimone 1
Chemical Reviews ( IF 51.4 ) Pub Date : 2017-03-15 00:00:00 , DOI: 10.1021/acs.chemrev.6b00834 Zachary G. Brill 1 , Matthew L. Condakes 1 , Chi P. Ting 1 , Thomas J. Maimone 1
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The pool of abundant chiral terpene building blocks (i.e., “chiral pool terpenes”) has long served as a starting point for the chemical synthesis of complex natural products, including many terpenes themselves. As inexpensive and versatile starting materials, such compounds continue to influence modern synthetic chemistry. This review highlights 21st century terpene total syntheses which themselves use small, terpene-derived materials as building blocks. An outlook to the future of research in this area is highlighted as well.
中文翻译：
在复杂的萜烯天然产物的全合成中浏览手性库
丰富的手性萜烯结构单元库（即“手性池萜烯”）长期以来一直是复杂天然产物（包括许多萜烯本身）化学合成的起点。作为廉价和通用的原料，此类化合物继续影响现代合成化学。这篇评论重点介绍了21世纪的萜烯全合成方法，这些合成方法本身使用萜烯衍生的小材料作为构建基块。还强调了该领域研究的前景。
更新日期：2017-06-28
中文翻译：
在复杂的萜烯天然产物的全合成中浏览手性库
丰富的手性萜烯结构单元库（即“手性池萜烯”）长期以来一直是复杂天然产物（包括许多萜烯本身）化学合成的起点。作为廉价和通用的原料，此类化合物继续影响现代合成化学。这篇评论重点介绍了21世纪的萜烯全合成方法，这些合成方法本身使用萜烯衍生的小材料作为构建基块。还强调了该领域研究的前景。
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