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Modification of Eu3+–beta-diketonate complex-intercalated LAPONITE® with a terpyridine-functionalized ionic liquid
RSC Advances ( IF 3.9 ) Pub Date : 2015-07-23 00:00:00 , DOI: 10.1039/c5ra09750a Yalan Yao 1, 2, 3 , Zhiqiang Li 1, 2, 3 , Huanrong Li 1, 2, 3
RSC Advances ( IF 3.9 ) Pub Date : 2015-07-23 00:00:00 , DOI: 10.1039/c5ra09750a Yalan Yao 1, 2, 3 , Zhiqiang Li 1, 2, 3 , Huanrong Li 1, 2, 3
Affiliation
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A lanthanide complex-based organic–inorganic hybrid material with intense luminescence has been obtained by modifying Eu3+–beta-diketonate complex-intercalated LAPONITE® with a terpyridine moiety-functionalized ionic liquid. Remarkable luminescence enhancement as well as improved thermal- and photo-stability were observed after modification with the functional ionic liquid. The ionic liquid is believed to coordinate to and sensitize Eu3+ ions as well as decrease proton concentration on LAPONITE® surfaces.
中文翻译：
用三联吡啶官能化的离子液体 对Eu 3+ –β-二酮酮酸酯络合物LAPONITE®的 改性
通过用三联吡啶部分官能化的离子液体修饰Eu 3+ -β-二酮酮络合物嵌入的LAPONITE®，可以获得具有强烈发光的基于镧系元素的有机-无机杂化材料。用功能性离子液体改性后，观察到显着的发光增强以及改善的热稳定性和光稳定性。据信该离子液体可与Eu 3+离子配位并使其敏化，并降低LAPONITE®表面上的质子浓度。
更新日期：2015-07-23
中文翻译：
用三联吡啶官能化的离子液体 对Eu 3+ –β-二酮酮酸酯络合物LAPONITE®的 改性
通过用三联吡啶部分官能化的离子液体修饰Eu 3+ -β-二酮酮络合物嵌入的LAPONITE®，可以获得具有强烈发光的基于镧系元素的有机-无机杂化材料。用功能性离子液体改性后，观察到显着的发光增强以及改善的热稳定性和光稳定性。据信该离子液体可与Eu 3+离子配位并使其敏化，并降低LAPONITE®表面上的质子浓度。
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