Liquid phase oxidation chemistry in continuous-flow microreactors,Chemical Society Reviews

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Liquid phase oxidation chemistry in continuous-flow microreactors
Chemical Society Reviews ( IF 40.4 ) Pub Date : 2015-07-23 00:00:00 , DOI: 10.1039/c5cs00447k
Hannes P. L. Gemoets _{1,

2,

3,

4,

5} , Yuanhai Su _{1,

2,

3,

4,

5} , Minjing Shang _{1,

2,

3,

4,

5} , Volker Hessel _{1,

2,

3,

4,

5} , Rafael Luque _{6,

7,

8,

9} , Timothy Noël _{1,

2,

3,

4,

5}

Affiliation

Continuous-flow liquid phase oxidation chemistry in microreactors receives a lot of attention as the reactor provides enhanced heat and mass transfer characteristics, safe use of hazardous oxidants, high interfacial areas, and scale-up potential. In this review, an up-to-date overview of both technological and chemical aspects of liquid phase oxidation chemistry in continuous-flow microreactors is given. A description of mass and heat transfer phenomena is provided and fundamental principles are deduced which can be used to make a judicious choice for a suitable reactor. In addition, the safety aspects of continuous-flow technology are discussed. Next, oxidation chemistry in flow is discussed, including the use of oxygen, hydrogen peroxide, ozone and other oxidants in flow. Finally, the scale-up potential for continuous-flow reactors is described.

中文翻译：

连续流微反应器中的液相氧化化学

微型反应器中的连续流液相氧化化学得到了广泛的关注，因为该反应器具有增强的传热和传质特性，危险氧化剂的安全使用，高界面面积和扩大规模的潜力。在这篇综述中，给出了连续流微反应器中液相氧化化学的技术和化学方面的最新概述。提供了传质和传热现象的描述，并推导了基本原理，可用于对合适的反应堆进行明智的选择。此外，还讨论了连续流技术的安全性。接下来，讨论了流动中的氧化化学，包括在流动中使用氧气，过氧化氢，臭氧和其他氧化剂。最后，描述了连续流反应器的放大潜力。

更新日期：2015-07-23

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