A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores,Angewandte Chemie International Edition

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A Pd@Zeolite Catalyst for Nitroarene Hydrogenation with High Product Selectivity by Sterically Controlled Adsorption in the Zeolite Micropores
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-06-13 07:10:32 , DOI: 10.1002/anie.201705761
Jian Zhang ₁ , Liang Wang ₁ , Yi Shao ₂ , Yanqin Wang ₂ , Bruce C. Gates ₃ , Feng‐Shou Xiao ₁

Affiliation

Palladium nanoparticles were fixed inside zeolite crystals to obtain a catalyst with superior selectivity in the hydrogenation of substituted nitroarenes with multiple reducible groups. In their Communication (DOI: 10.1002/anie.201703938), L. Wang, F.-S. Xiao, and co-workers show that the high selectivity is due to the sterically controlled adsorption of the nitroarenes on the palladium nanoparticles within the zeolite micropores.

中文翻译：

沸石微孔中立体控制吸附的Pd @沸石催化硝基芳烃加氢的高产物选择性催化剂

将钯纳米颗粒固定在沸石晶体内部，以获得具有多个可还原基团的取代硝基芳烃氢化中具有优异选择性的催化剂。在他们的交流中（DOI：10.1002 / anie.201703938），L.Wang，F.-S. Xiao和他的同事表明，高选择性是由于硝基芳烃在沸石微孔内钯纳米颗粒上的空间控制吸附。

更新日期：2017-06-14

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