Hydrolysis-Initiated Domino Process on the Rim of Open-Cage C60 Derivatives Including Decarbonylation and Double Dehydration.,ChemPlusChem

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Hydrolysis-Initiated Domino Process on the Rim of Open-Cage C60 Derivatives Including Decarbonylation and Double Dehydration.
ChemPlusChem ( IF 3.0 ) Pub Date : 2017-05-23 , DOI: 10.1002/cplu.201700198
Hao Zhang ₁ , Liang Xu ₁ , Liangbing Gan _{1,

2}

Affiliation

Hydrolysis of an open-cage C60 derivative in a mixture of HCl/AcOH/H2 O resulted in removal of two hydroxyl groups, one carbonyl group and one aniline group in one step. A domino mechanism is proposed for the process. The newly formed open-cage C60 derivative has three carbonyl groups on the rim of the orifice, one of which could be converted into an oxime group by treatment with hydroxylamine.

中文翻译：

基于开笼C60衍生物（包括脱羰基和双脱水）的水解引发多米诺法。

在HCl / AcOH / H2 O的混合物中水解开笼C60衍生物可一步除去两个羟基，一个羰基和一个苯胺基。为该过程提出了一种多米诺机制。新形成的开笼式C60衍生物在孔的边缘具有三个羰基，其中一个可以通过用羟胺处理转化为肟基。

更新日期：2017-05-23

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