Recent advances of metal–metal oxide nanocomposites and their tailored nanostructures in numerous catalytic applications,Journal of Materials Chemistry A

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Recent advances of metal–metal oxide nanocomposites and their tailored nanostructures in numerous catalytic applications
Journal of Materials Chemistry A ( IF 10.7 ) Pub Date : 2017-04-18 00:00:00 , DOI: 10.1039/c7ta02116j
Chaiti Ray _{1,

2,

3,

4} , Tarasankar Pal _{1,

2,

3,

4}

Affiliation

The skilful synthesis of nanohybrids composed of noble metals (Au, Ag, Pt and Pd, as well as AuAg alloy) and metal oxides (ZnO, TiO₂, Cu₂O, MnO₂, Fe₂O₃, WO₃ and CeO₂) has received considerable attention for applications in photocatalysis, solar cells, drug delivery, surface enhanced Raman spectroscopy and many other important areas. The overall architecture of nanocomposites is one of the most important factors dictating the physical properties of nanohybrids. Noble metals can be coupled to metal oxides and metal chalcogenides to yield diverse nanostructures, including noble metal decorated-metal oxide nanoparticles (NPs), nanoarrays, noble metal/metal oxide core/shell, noble metal/metal oxide yolk/shell and Janus noble metal–metal oxide nanostructures. In this review, we focus on the significant application based advances in neat and tailored nanostructures of noble metal–metal oxide nanohybrids and touched upon chalcogenides also. The improvement in performance in representative energy conversion, electrochemical water splitting, photocatalytic hydrogen generation, photocatalytic CO₂ reduction, photocatalytic degradation of organic pollutants and dye-sensitized solar cell (DSSCs) applications is discussed. Finally, we conclude with a perspective on the future direction and prospects of these controllable nanohybrid materials.

中文翻译：

金属-金属氧化物纳米复合材料及其定制的纳米结构在众多催化应用中的最新进展

由贵金属（Au，Ag，Pt和Pd以及AuAg合金）和金属氧化物（ZnO，TiO ₂，Cu ₂ O，MnO ₂，Fe ₂ O ₃，WO ₃和CeO ₂）组成的纳米杂化物的熟练合成）在光催化，太阳能电池，药物输送，表面增强拉曼光谱学和许多其他重要领域中的应用受到了相当多的关注。纳米复合材料的整体结构是决定纳米杂化物物理性质的最重要因素之一。贵金属可以与金属氧化物和金属硫族化物偶联以产生多种纳米结构，包括贵金属装饰的金属氧化物纳米颗粒（NP），纳米阵列，贵金属/金属氧化物核/壳，贵金属/金属氧化物卵黄/壳和Janus贵金属金属-金属氧化物纳米结构。在这篇综述中，我们将重点放在贵金属-金属氧化物纳米杂化物的纯净和量身定制的纳米结构的重要应用基础上，并涉及硫族化物。代表能量转换的性能改善，_{讨论了2的}还原，有机污染物的光催化降解以及染料敏化太阳能电池（DSSC）的应用。最后，我们以对这些可控纳米杂化材料的未来方向和前景的展望作为结束。

更新日期：2017-05-09

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