Ammonia Oxide as a Building Block for High‐Performance and Insensitive Energetic Materials,Angewandte Chemie International Edition

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Ammonia Oxide as a Building Block for High‐Performance and Insensitive Energetic Materials
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-04-24 , DOI: 10.1002/anie.201702285
Yongxing Tang ₁ , Lauren A. Mitchell ₂ , Gregory H. Imler ₃ , Damon A. Parrish ₃ , Jean'ne M. Shreeve ₁

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3,5‐Dinitrimino‐1,2,4‐triazole (2) with three protons has the potential of deprotonation to form energetic salts. Neutralization of 2 with 50 % hydroxylamine in varying molar ratios leads to the formation of the corresponding mono/dihydroxylammonium energetic salts. Additionally compound 5, an ammonia oxide adduct of dihydroxylammonium 3,5‐dinitramino‐1,2,4‐triazolate, was prepared when excess hydroxylamine was used. The structures of 3–5 are supported by single‐crystal X‐ray diffraction. The energetic properties of the new materials are competitive. Utilization of ammonia oxide adducts in hydroxylammonium energetic salts could lead to future practical applications as energetic materials.

中文翻译：

氧化氨作为高性能和不敏感的高能材料的基础

具有三个质子的3,5-二氨基三甲基，1,2,4-三唑（2）具有去质子化形成高能盐的潜力。用不同摩尔比的50％羟胺对2进行中和，导致形成相应的单/二羟基铵高能盐。另外，当使用过量的羟胺时，还制备了化合物5，即3,5-二氨基氨基1,2,4-三唑醇二羟基铵的氨氧化物加合物。3 – 5的结构由单晶X射线衍射支持。新材料的能量特性具有竞争力。在羟基铵高能盐中使用氧化氨加合物可能导致将来作为高能材料的实际应用。

更新日期：2017-04-24

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