An Efficient Iron(III)‐Catalyzed Aerobic Oxidation of Aldehydes in Water for the Green Preparation of Carboxylic Acids,Angewandte Chemie International Edition

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An Efficient Iron(III)‐Catalyzed Aerobic Oxidation of Aldehydes in Water for the Green Preparation of Carboxylic Acids
Angewandte Chemie International Edition ( IF 16.1 ) Pub Date : 2017-03-02 , DOI: 10.1002/anie.201612225
Han Yu _{1,

2} , Shi Ru ₁ , Guoyong Dai ₁ , Yongyan Zhai ₁ , Hualin Lin ₁ , Sheng Han ₁ , Yongge Wei _{2,

3}

Affiliation

The first example of a heterogeneous iron(III)‐catalyzed aerobic oxidation of aldehydes in water was developed. This method utilizes 1 atmosphere of oxygen as the sole oxidant, proceeds under extremely mild aqueous conditions, and covers a wide range of various functionalized aldehydes. Chromatography is generally not necessary for product purification. Its operational simplicity, gram‐scale oxidation, and the ability to successively reuse the catalyst, make this new methodology environmentally benign and cost effective. The generality of this methodology gives it the potential to be used on an industrial scale.

中文翻译：

高效铁（III）催化水中的醛的好氧氧化，用于绿色制备羧酸

开发了第一个非均质铁（III）催化水中醛的需氧氧化的例子。该方法利用1个大气压的氧气作为唯一的氧化剂，在极其温和的水性条件下进行，并涵盖了各种功能化的醛类。色谱法通常对于产品纯化不是必需的。它的操作简便性，克级氧化性以及连续重复使用催化剂的能力，使这种新方法在环境方面无害且具有成本效益。这种方法的通用性使其有可能在工业规模上使用。

更新日期：2017-03-02

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